글번호
146553
작성일
2021.05.12
수정일
2021.05.12
작성자
sm_iams
조회수
601

[2020] Instability and transformation kinetics of the reconstructions in carburized W(1 1 0)

[2020] Instability and transformation kinetics of the reconstructions in carburized W(1 1 0) 첨부 이미지

  We investigate the instability and transformation kinetics of the carbon-induced surface reconstructions on W(1 1 0) by the low temperature scanning tunneling microscopy. R(15 3 × ) reconstruction, a moiré pattern of W2C(0 0 0 1) bi-layer on W(1 1 0), is the most carbon-rich reconstruction on the carburized W(1 1 0), which gradually transforms to the most carbon-poor R(15 12 × ) reconstruction by repeated annealing at around 2070 K. In between, various reconstructions, albeit not globally ordered, develop. Notable is that all the ob-served reconstructions are invariably composed of only two kinds of building blocks, namely A-block and B-block. A-block is the surface unit cell of the R(15 3) × reconstruction. During the transformation, the virtually carbon free B-block is created at the cost of two neighboring A-blocks by the annealing. The robustness of the block structure allows us to perform a coarse-grained kinetic Monte Carlo simulation of the transformation i terms of the creation and diffusion of B-blocks on the R(15 3) × lattice that is initially entirely tiled by A-blocks. We find that the transformation kinetics is governed by both the anisotropic creation and diffusion of B-block that are attributed to the instability of A-block driven by the anisotropic compressive stress in it.

구성원
Jae-Sung Kim
학술지명
Applied Surface Science
535
시작 페이지
147663
게재년
2020
첨부파일
첨부파일이(가) 없습니다.